Mobile high resolution xenon nuclear magnetic resonance spectroscopy in the earth's magnetic field.
نویسندگان
چکیده
Conventional high resolution nuclear magnetic resonance (NMR) spectra are usually measured in homogeneous, high magnetic fields (>1 T), which are produced by expensive and immobile superconducting magnets. We show that chemically resolved xenon (Xe) NMR spectroscopy of liquid samples can be measured in the Earth's magnetic field (5 x 10(-5) T) with a continuous flow of hyperpolarized Xe gas. It was found that the measured normalized Xe frequency shifts are significantly modified by the Xe polarization density, which causes different dipolar magnetic fields in the liquid and in the gas phases.
منابع مشابه
Imaging of laser-polarized solid xenon.
The enhanced spin polarization produced by optical pumping of gaseous rubidium/xenon samples has made possible a number of recent experiments in nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI). Here we report MRI of laser-polarized xenon in the solid phase at low temperature. Due to the high xenon density in the solid phase and the enhanced spin polarization, ...
متن کاملResolution of (129)Xe chemical shifts at ultralow magnetic field.
In high-field nuclear magnetic resonance (NMR) spectroscopy, the sensitivity of the xenon chemical shift to its environment1 has been exploited to study porosity and surface interactions in materials2, as well as to probe xenon interactions with molecules3 and proteins4 in solution. In recent years, polarization enhancement through optical pumping5 techniques has further advanced the utility of...
متن کاملHigh-resolution NMR of static samples by rotation of the magnetic field.
Mechanical rotation of a sample at 54.7 degrees with respect to the static magnetic field, so-called magic-angle spinning (MAS), is currently a routine procedure in nuclear magnetic resonance (NMR). The technique enhances the spectral resolution by averaging away anisotropic spin interactions thereby producing isotropic-like spectra with resolved chemical shifts and scalar couplings. It should ...
متن کاملروشهای طیفسنجی در آنالیز همزمان مواد منفجره
Simultaneous analysis of explosives to identify, determine the purity and eliminate environmental pollution requires rapid, simple and cheap methods. Spectrophotometries method (UV-Vis), high-field proton nuclear magnetic resonance (1H-NMR), Raman spectroscopy and near infrared (NIR) are common methods that are applicable in two ways of direct and indirect in simultaneous analysis. In this poin...
متن کاملSolid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs)
Nuclear Magnetic Resonance (NMR) spectroscopy is a well-established method for the investigation of various types of porous materials. During the past decade, metal–organic frameworks have attracted increasing research interest. Solid-state NMR spectroscopy has rapidly evolved into an important tool for the study of the structure, dynamics and flexibility of these materials, as well as for the ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Physical review letters
دوره 94 19 شماره
صفحات -
تاریخ انتشار 2005